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US Patent 9379405 Polymer electrolyte membrane having alkylether graft chain

Patent 9379405 was granted and assigned to Kanagawa University on June, 2016 by the United States Patent and Trademark Office.

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Patent
Patent
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Patent attributes

Patent Applicant
Kanagawa University
Kanagawa University
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Current Assignee
Kanagawa University
Kanagawa University
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Patent Jurisdiction
United States Patent and Trademark Office
United States Patent and Trademark Office
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Patent Number
93794050
Patent Inventor Names
Yasunari Maekawa0
Kazuyuki Enomoto0
Nobuhiro Kihara0
Date of Patent
June 28, 2016
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Patent Application Number
139235970
Date Filed
June 21, 2013
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Patent Primary Examiner
‌
Peter D. Mulcahy
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Patent abstract

An electrolyte membrane having alkylether graft chains for use in a fuel cell produced by a method of producing an electrolyte membrane for use in a fuel cell, including: performing radiation-induced graft polymerization of a vinyl monomer having nucleophilic functional groups, the vinyl monomer selected from an acylvinyl ether derivative, a styrene derivative, and a methacrylic acid derivative, with a polymer substrate comprising a polymer selected from a fluorine-containing polymer, an olefinic polymer, and an aromatic polymer; deprotecting the nucleophilic functional group, which is protected by an ester bond, of a graft chain on the polymer substrate introduced by the radiation-induced graft polymerization; and introducing an alkylethersulfonic acid structure into the deprotected nucleophilic functional group of the graft chain, by use of an electrophilic reagent selected from cyclic sulfonic acid ester and alkylhalide-sulfonate.

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