US Patent 7703519 Combined hydrogen production and unconventional heavy oil extraction

A method of producing hydrogen and extracting heavy oil from underground reserves is provided. This method includes providing a carbon monoxide source stream and a water vapor stream to a first reactor, wherein the first reactor comprises a water shift reactor and a membrane-type separation device. This method also includes separating the products of the water shift reactor, thereby producing at least a hydrogen-rich stream, and a high pressure off-gas stream. This method also includes providing the high pressure off-gas stream and an oxidant stream to a combustion chamber. This method also includes combusting the oxidant stream and the high pressure off-gas stream as at least part of a combustion cycle thereby producing a hot injection gas stream. This method also includes combining the hot injection gas stream with a liquid water stream, wherein the combined stream may be used to heat the underground reserve sufficiently to release petroleum hydrocarbons therefrom.