Patent attributes
The present invention relates to a process for preparing organopolysiloxanes by reacting halosilane with alcohol and water in the presence of the desired organopolysiloxane in a reaction unit comprising a distillation column, optionally a reflux condenser, and a vessel already containing desired organopolysiloxane, by heating the vessel contents to boiling under reflux, introducing halosilane into the column above the lower column end, removing hydrogen halide from the distillation column and continuously removing organopolysiloxane from the vessel at the same rate in which it is formed, by constantly adding halosilane, alcohol and water to the reaction unit in such amounts that more water is always present in the reaction unit than is consumed by the added Si-halogen units of the halosilanes.