US Patent 11440300 Multilayer polyproylene film

Multilayer film comprising at least a skin layer, a core layer and an inner layer, the skin layer comprising a homo polypropylene or a random propylene ethylene copolymer including up to 2.5 wt.-% units derived from ethylene, the homopolypropylene or the random propylene ethylene copolymer having a MFR2 (ISO1 133, 230° C.) of 2.0 to 20 g/10 min and a melting temperature (Tm) of above 148° C. measured by DSC according to ISO 11357-3:1999 and a scan rate of 10° C./min; the core layer comprising a mixture obtainable by melt blending 20 to 100 wt.-% of a random heterophasic copolymer and 0 to 80 wt.-% of styrene based TPE, whereby the random heterophasic copolymer has a melting temperature (Tm) of 134° C.-148° C. measured by DSC according to ISO 11357-3:1999 and a scan rate of 10° C./min and includes a propylene ethylene copolymer rubber; and whereby the styrene based TPE has a styrene content of from 5 to 20 wt.-%, and the inner layer comprising a random propylene ethylene copolymer having a melting temperature (Tm) from 132° C. to 144° C. measured by DSC according to ISO 11357-3:1999 and a scan rate of 10° C./min, wherein the multilayer film is free of phthalic acid esters as well as decomposition products thereof.