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US Patent 11358134 Heterobimetallic catalysts and site-differentiated ligands for preparation thereof

Patent 11358134 was granted and assigned to University of Houston System on June, 2022 by the United States Patent and Trademark Office.

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Phosphine phosphonate and phenoxyphosphine ligands bearing polyethylene glycol (PEG) chains are used as described herein to produce heterobimetallic catalysts. The ligands can be metallated selectively with palladium or nickel and secondary metal ions to provide well-defined heterobimetallic compounds. These heterobimetallic complexes exhibit accelerated reaction rates and greater thermal stability in olefin polymerization compared to other catalysts.

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