An anhydrous heat transfer medium, comprising any one or a combination of at least two of cis-1-chloro-3,3,3-trifluoropropene, cis-1,1,1,4,4,4-hexafluorobutene or perfluorobutane methyl ether. The heat transfer medium does not require an external device to perform work on the heat transfer medium during a heat transfer process, and is anhydrous, non-combustible, non-conductive and environmentally friendly.