Electrochemical devices that include porous layers, and associated methods, are generally described. In certain cases, the electrochemical device includes a first layer (e.g., a porous coating containing nanoparticles) between an anode and a separator, and a second layer (e.g., another porous coating containing nanoparticles) between a cathode and the separator. The first layer and/or the second layer may have a relatively high porosity, even after the application of an applied pressure to the electrochemical device. The presence of the first layer and the second layer in the electrochemical device may mitigate the occurrence of certain problematic phenomena during cycling of the electrochemical device.